日本科学与技术高等研究院Prof. Donglin Jiang 12月2日上午学术报告

Presenter:Prof.Donglin Jiang(Japan Advanced Institute of Science and Technology)

Topic:Covalent Organic Frameworks: Opportunities and Challenges

Time: 9:30 AM, Dec. 02^nd (Friday)

Location: Conference Room B, BLDG 909-1F

Abstract

Two-dimensional covalent polymers and organic frameworks are a class of crystalline polymers that enable the incorporation of organic building blocks into periodically aligned structures. In recent years, we have explored the design principle, synthetic reactions, structural diversity, functional design and materials applications.[1-10] One significant feature is that the merge of covalent bonds and noncovalent interactions enables the precise control over primary and high-order structures. The geometry-directed covalent bonding enables the growth of two-dimensional atomic layer in which the primary-order structures are precisely controlled. The noncovalent π-π interactions guided by the total crystal stacking energy encode the ordered primary-order structure into high-order structures to construct periodically aligned polymer skeletons and nanosized unidirectional channels. In this seminar, I will discuss the chemistry, opportunity and challenges of COFs.

References:

[1] Jiang, D. et al, Chem. Soc. Rev. 2012, 41, 6010.

[2] Jiang, D. et al, Angew. Chem., Int. Ed. 2008, 47, 8826 (VIP).

[3] Jiang, D. et al, Nat. Commun. 2011, 2:536.

[4] Jiang, D. et al, Nat. Commun. 2013, 4: 2736.

[5] Jiang, D. et al, Nat. Chem. 2014, 6, 564.

[6] Jiang, D. et al, Nat. Commun. 2015, 6:7786.

[7] Jiang, D. et al, Nat. Chem. 2015, 9, 905.

[8] Jiang, D. et al, Nat. Mater. 2016, 15, 722.

[9] Jiang, D. et al, Nat. Commun. 2016, 7:12325.

[10] Jiang, D. et al, Nat. Rev. Mater. 2016, 1:16068. DOI:10.1038/natrevmats.2016.68.

Biography

Education

March 1998:      Ph. D, Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

Academic Carrier

April 1997–June 1998:              JSPS Fellow

June 1998–September 2000:          Assistant Professor, The University of Tokyo

October 2000–April 2005:          Group Leader, JST ERATO Nanospace Project, JST

May 2005–December, 2015:     Associate Professor, Institute for Molecular Sciences and Associate Professor, Department of Structural Molecules, The Graduate University of Advanced Studies

October 2005–March 2009:              Researcher, PRESTO, JST

October 2009–March 2013:              Researcher, PRESTO, JST

January, 2016–present:              Professor, Japan Advanced Institute of Science and

Technology

Awards

(1) Wiley Award 2006 of Society of Polymer Science, Japan (SPSJ).

(2) The Young Scientists' Prize 2006, The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology.

Research Interests

Covalent organic frameworks (COFs)

Conjugated microporous polymers (CMPs)

Contact: Prof. Lifeng Chi