王照奎教授课题组在Angew. Chem. Int. Ed.上发表论文

题目：

Vertically Concentrated Quantum Wells Enabling Highly Efficient Deep-Blue Perovskite Light-Emitting Diodes

作者：

Yu Xia¹, Bin Song¹, Zhipeng Zhang², Kai-Li Wang¹, Yu-Han Li¹, Nan Li¹, Chun-Hao Chen¹, Jing Chen¹, Guichuan Xing², Zhao-Kui Wang¹*

单位：

¹Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China.

²Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida daUniversidade, Taipa 999078 Macao SAR, China.

摘要：

Deep-blue perovskite light-emitting diodes (PeLEDs) based on quasi-two-dimensional (quasi-2D) systems exist heightened sensitivity to the domain distribution. The top-down crystallization mode will lead to a vertical gradient distribution of quantum well (QW) structure, which is unfavorable for deep-blue emission. Herein, a thermal gradient annealing treatment is proposed to address the polydispersity issue of vertical QWs in quasi-2D perovskites. The formation of large-n domains at the upper interface of the perovskite film can be effectively inhibited by introducing a low-temperature source in the annealing process. Combined with the utilization of NaBr to inhibit the undesirable n=1 domain, a vertically concentrated QW structure is ultimately attained. As a result, the fabricated device delivers a narrow and stable deep-blue emission at 458 nm with an impressive external quantum efficiency (EQE) of 5.82%. Green and sky-blue PeLEDs with remarkable EQE of 21.83% and 17.51% are also successfully achieved, respectively, by using the same strategy. The findings provide a universal strategy across the entire quasi-2D perovskites, paving the way for future practical application of PeLEDs.

影响因子：

16.823

分区情况：

一区

链接：

https://onlinelibrary.wiley.com/doi/10.1002/anie.202403739