姓名:屠迎锋
职称:教授、博士生导师
部门:材料学院
联系方式:
Tel: 86-512-65882130 (o)
Email:tuyingfeng@suda.edu.cn
学历及学术经历:1994.9-1998.7北京大学化学与分子工程学院,获学士学位,导师宛新华教授;1998.9-2003.7北京大学高分子化学与物理系,获博士学位,导师周其凤院士(与香港中文大学吴奇院士联合培养);2004.2-2009.10美国阿克伦大学(The University of Akron)高分子科学与工程系副研究员(博士后),合作导师程正迪院士和Frank W. Harris教授。2009.11加入18新利体育 ,任教授,博士生导师。迄今在国内外核心化学期刊如Journal of the American Chemical Society、Angewandte Chemie International Edition等发表SCI论文100余篇,被他引2000多次。主持4项国家自然科学基金项目,参与1项科技部“973”项目。授权中国发明专利8项。与杜邦(中国)、华润(包装)、开滦(集团)有限责任公司等多个企业有良好的合作研究关系。
研究领域:嵌段共聚物和嵌段分子。基于环状或笼状分子的受限结构,利用高分子物理方面的理论指导嵌段共聚物/超分子嵌段共聚物以及精密嵌段分子的设计和合成,研究其结构和性能的关系,得到高性能嵌段共聚物弹性体或超分子液晶等材料。主要包括以下三个研究方向:1)以环状寡聚酯为单体,通过课题组创立的开环-缩合级联聚合方法,合成高性能聚酯或聚醚酯多嵌段共聚物弹性体(TPEE);2)基于共价聚合和超分子聚合两种策略合成基于配位键的金属-超分子多嵌段共聚物;3)基于笼状分子纳米粒子(富勒烯、POSS等)的嵌段分子的合成及其自组装构筑新型超分子液晶。
本课题组招收化学、材料、应化、化工方面的学生,欢迎有兴趣的本科生、研究生、博士后加盟。
代表性论文
1. Zhikai Li, Yiming Li, Yiming Zhao, Heng Wang, Yuan Zhang, Bo Song, Xiaohong Li, Shuai Lu, Xin-Qi Hao, Saw-Wai Hla,* Yingfeng Tu,* and Xiaopeng Li* “Synthesis of Metallopolymers and Direct Visualization of the Single Polymer Chain” Journal of the American Chemical Society,2020, 142, 6196-6205
2. Lingfeng Gao, Zhichao Ji, Yiming Zhao, Yuanli Cai, Xiaohong Li, Yingfeng Tu* “Synthesis and Solution Self-Assembly Properties of Cyclic Rod−Coil Diblock Copolymers” ACS Macro Letters,2019, 8, 1564−1569.
3. 屠迎锋. “级联聚合反应”高分子学报(Acta Polymerica Sinica),2019, 11, 1146-1155.
4. Wanming Wang, Feng Wu, Huanjun Lu, Xiaohong Li,* Xiaoming Yang, Yingfeng Tu* “A Cascade Polymerization Method for the Property Modification of Poly(butylene terephthalate) by the Incorporation of Isosorbide” ACS Applied Polymer Materials,2019, 1, 2313−2321.
5. Siyuan Xu, Feng Wu, Zhikai Li, Xiang Zhu, Xiaohong Li,* Lian Wang, Yongjin Li, Yingfeng Tu* “A green cascade polymerization method for the facile synthesis of sustainable poly(butylene-co-decylene terephthalate) copolymers” Polymer,2019, 178, 121591.
6. Lingfeng Gao, Joongsuk Oh, Yingfeng Tu,* Taihyun Chang* and Christopher Y. Li “Glass transition temperature of cyclic polystyrene and the linear counterpart contamination effect” Polymer,2019, 170, 198-203.
7. Yating Zhao, Lei Liu, Yingfeng Tu* and Hai-Chen Wu* “Investigating the effect of mono- and multivalent counterions on the conformation of poly(styrenesulfonic acid) by nanopores” Electrophoresis, 2019, 40, 2180-2185.
8. Peng Shen, Xiaoyan Zhang, Huanjun Lu, Zebin Su, Yi Zhou,* Bo Song, Xiaohong Li, Xiaoming Yang, Yingfeng Tu* and Christopher Y. Li “Effect of Fullerene Volume Fraction on Two-Dimensional Crystal Constructed Supramolecular Liquid Crystals” Chemistry - An Asian Journal, 2019, 14, 125-129.
9. Chong He, Xiang Zhu, Xiao-Hong Li, Xiao-Ming Yang, and Ying-Feng Tu* “Thermodynamics of Aromatic Cyclic Ester Polymerization in Bulk” Chinese Journal of Polymer Science, 2019, 37, 89-93.
10. Kuan Liu, Shuang Chen, Jionghua Wu, Huiyin Zhang, Minchao Qin, Xinhui Lu, Yingfeng Tu,* Qingbo Meng* and Xiaowei Zhan* “Fullerene derivative anchored SnO2 for high-performance perovskite solar cells” Energy & Environmental Science, 2018, 11, 3463-3471.
11. Yi Hu, Kuan-Yi Wu, Tiantian Zhu, Peng Shen, Yi Zhou, Xiaohong Li, Chien-Lung Wang, Yingfeng Tu,* and Christopher Y. Li “Unique Supramolecular Liquid-Crystal Phases with Different Two-Dimensional Crystal Layers” Angewandte Chemie International Edition, 2018, 57, 13454 –13458; Angewandte Chemie, 2018, 130, 13642–13646.
12. Lingfeng Gao, Joongsuk Oh, Yingfeng Tu,* and Taihyun Chang* “Preparation of Low Molecular Weight Cyclic Polystyrenes with High Purity via Liquid Chromatography at the Critical Condition” Polymer, 2018, 135, 279-284.
13. Zhikai Li, Jiali Gu, Shengli Qi, Dezhen Wu, Lingfeng Gao, Ze Chen, Jun Guo, Xiaohong Li, Yong Wang, Xiaoming Yang, and Yingfeng Tu* “Shackling Effect Induced Property Differences in Metallo-Supramolecular Polymers” Journal of the American Chemical Society, 2017, 139, 14364-14367.
14. Minzhi Zhang, Jiali Gu, Xiang Zhu, Lingfeng Gao, Xiaohong Li, Xiaoming Yang, Yingfeng Tu,* Christopher Y. Li “Synthesis of poly(butylene terephthalate)-block-poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) multiblock terpolymers via a facile PROP method” Polymer, 2017, 130, 199-208.
15. Weichun Huang, Qiwei Pan, Hao Qi, Xiaohong Li, Yingfeng Tu,* Christopher Y. Li,* “Poly(butylene terephthalate)-b-poly(ethylene oxide) alternating multiblock copolymers: synthesis and application in solid polymer electrolytes” Polymer, 2017, 128, 188-199.
16. Tiantian Zhu, Xiaoyan Zhang,* Zhikai Li, Chih-Hao Hsu, Wei Chen, Toshikazu Miyoshi, Xiaohong Li, Xiaoming Yang, Yingfeng Tu* and Christopher Y. Li “Controlling the enthalpy–entropy competition in supramolecular fullerene liquid crystals by tuning the flexible chain length” Chemical Communications, 2017, 8336--8339.
17. Min Lu, Xiang Zhu, Xiao-hong Li, Xiao-ming Yang and Ying-feng Tu* “Synthesis of Cyclic Oligo(ethylene adipate)s and their Melt Polymerization to Poly(ethylene adipate)” Chinese Journal of Polymer Science, 2017, 35, 1051-1060.
18. Dong-xue Chen, Ling-feng Gao, Xiao-hong Li* and Ying-feng Tu* “Precise Molecular Weight Determination and Structure Characterization of End-functionalized Polymers: an NMR Approach via Combination of One-dimensional and Two-dimensional Techniques”Chinese Journal of Polymer Science, 2017, 35, 681-692.
19. Xiang Zhu, Jiali Gu, Xiaohong Li, Xiaoming Yang, Lian Wang, Yongjin Li, He Li and Yingfeng Tu* “PROP: an in situ cascade polymerization method for the facile synthesis of polyesters” Polymer Chemistry, 2017, 8, 1953-1962.
20. Jianying Chen, Dongxue Chen, Weichun Huang, Xiaoming Yang,* Xiaohong Li,* Yingfeng Tu,* and Xiulin Zhu “A One Pot Facile Synthesis of Poly(butylene terephthalate)-block-Poly(tetramethylene oxide) Alternative Multiblock Copolymers via PROP Method” Polymer, 2016, 107, 29-36.
21. Lingfeng Gao, Joongsuk Oh, Taihyun Chang, Dongxue Chen, Xiaohong Li, Xiaoming Yang, Yingfeng Tu,* Xiulin Zhu and Christopher Y. Li “A nearly quantitative synthetic approach towards monocyclic polystyrenes and the solvent, concentration and molecular weight effect on cyclic yield”Polymer, 2016, 101, 379-387.
22. Yanhong Wu, Rui Cao, Gaoxiang Wu, Weichun Huang, Ze Chen, Xiaoming Yang,* Yingfeng Tu* “From ultratough artificial nacre to elastomer: Poly (n-butyl acrylate) grafted graphene oxide nanocomposites” Composites: Part A, 2016, 88, 156–164.
23. Xiaoyan Zhang, Chih-Hao Hsu, Xiangkui Ren, Yan Gu, Bo Song, Hao-Jan Sun, Shuang Yang, Erqiang Chen, Yingfeng Tu,* Xiaohong Li, Xiaoming Yang, Yaowen Li, and Xiulin Zhu* “Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals” Angewandte Chemie International Edition, 2015, 54, 114-117.
24. Shuang Chen, Dongxue Chen, Min Lu, Xin Zhang, He Li, Xiaoyan Zhang, Xiaoming Yang, Xiaohong Li,* Yingfeng Tu* and Christopher Y. Li “Incorporating Pendent Fullerenes with High Refractive Index Backbones: A Conjunction Effect Method for High Refractive Index Polymers” Macromolecules, 2015, 48, 8480−8488.
25. Yanhong Wu, Rui Cao, Liangliang Ji, Weichun Huang, Xiaoming Yang* and Yingfeng Tu* “Synergistic toughening of bioinspired artificial nacre by polystyrene grafted graphene oxide” RSC Advances, 2015, 5, 28085–28091.
26. Jun Wu, Tao-guang Qu, Ling-feng Gao, Xiao-ming Yang, Xiao-hong Li, Ying-feng Tu* and Xiu-lin Zhu “Special Odd-Even Effect of Degree of Oligomerization on Properties of Cyclic Oligoesters” Chinese Journal of Polymer Science, 2015, 33, 1069-1073.
27. Yingfeng Tu,* Yan Gu, Ryan M. Van Horn, Maxim Mitrokhin, Frank W. Harris* and Stephen Z. D. Cheng “A synthetic approach towards micron-sized smectic liquid crystal capsules via the diffusion controlled swelling method” Polymer Chemistry, 2015, 6, 2551–2559.
28. Liangliang Ji, Xiaofang Chen, Yanhong Wu, Xiaoming Yang,* Yingfeng Tu* “Influence of liquid crystalline formation on the phase behavior of side-chain liquid crystalline block copolymers” Polymer, 2015, 61, 147-154.
29. Yingfeng Tu,* Zhichao Ji, Xiaoming Yang, Xinhua Wan, Qi-Feng Zhou “Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod–Coil Block Copolymer” Macromolecular Rapid Communications, 2014, 35, 1795−1800.
30. Honghong Yan, Shuang Chen, Min Lu, Xiang Zhu, Yanqing Li, Dezhen Wu, Yingfeng Tu* and Xiulin Zhu “Side-chain fullerene polyesters: a new class of high refractive index polymers” Materials Horizons, 2014, 1, 247-250.
31. Yanhong Wu, Chengxin Guo, Na Li, Liangliang Ji, Yaowen Li, Yingfeng Tu,* Xiaoming Yang* “Three-dimensional Interconnected Nanocarbon Hybrid Prepared by One-pot Synthesis Method with Polypyrrole-based Nanotube and Graphene and the Application in High-performance Capacitance” Electrochimica Acta, 2014, 146, 386–394.
32. Weichun Huang, Sheng Wang, Chengxin Guo, Xiaoming Yang,* Yaowen Li, Yingfeng Tu* “Synthesis and characterization of well-defined poly(L-lactide) functionalized graphene oxide sheets with high grafting ratio prepared through click chemistry and supramolecular interactions” Polymer, 2014, 55, 4619-4626.
33. Chao Li, Xiaoming Yang, Yue Zhao, Pan Zhang, Yingfeng Tu,* Yaowen Li* “Hole extraction layer utilizing well defined graphene oxide with multiple functionalities for high-performance bulk heterojunction solar cells” Organic Electronics, 2014, 15, 2868-2875.
34. Chengxin Guo, Liangliang Ji, Yaowen Li, Xiaoming Yang,* Yingfeng Tu* “Crystallization Behavior of Spray-Dried and Freeze-Dried Graphene Oxide/Poly(trimethylene terephthalate) Composites”Journal of Applied Polymer Science, 2014, 131, 40332.
35. Weichun Huang, Yingbo Wan, Jianying Chen, Qiaozhen Xu, Xiaohong Li,* Xiaoming Yang, Yaowen Li and Yingfeng Tu*“One pot synthesis and characterization of novel poly(ether ester) mutiblock copolymers containing poly(tetramethylene oxide) and poly(ethylene terephthalate)”Polymer Chemistry,2014, 5, 945-954.
36. Chengxin Guo, Na Li, Liangliang Ji, Yaowen Li, Xiaoming Yang,* Yun Lu,* Yingfeng Tu* “N- and O-doped carbonaceous nanotubes from polypyrrole for potential application in high-performance capacitance” Journal of Power Sources, 2014, 247, 660-666.
37. Qiaozhen Xu, Jianying Chen, Weichun Huang, Taoguang Qu, Xiaohong Li, Yaowen Li, Xiaoming Yang, and Yingfeng Tu* “One Pot, One Feeding Step, Two-Stage Polymerization Synthesis and Characterization of (PTT-b-PTMO-b-PTT)n Multiblock Copolymers” Macromolecules, 2013, 46, 7274-7281.
38. Chao Li, Yujin Chen, Yue Zhao, Huifang Wang, Wei Zhang, Yaowen Li,* Xiaoming Yang, Changqi Ma, Liwei Chen,* Xiulin Zhu and Yingfeng Tu* “Acceptor-Donor-Acceptor Based Small Molecules with Varied Crystallinity: Processing Additive Induced Nanofibril in Blend Film for Photovoltaic Application” Nanoscale,2013, 5, 9536-9540.
39. Xiaoming Yang, Chengxin Guo, Liangliang Ji, Yaowen Li, and Yingfeng Tu* “Liquid Crystalline and Shear-Induced Properties of an Aqueous Solution of Graphene Oxide Sheets” Langmuir, 2013, 29, 8103-8107.
40. Pan Zhang, Chao Li, Yaowen Li,* Xiaoming Yang, Liwei Chen, Bin Xu, Wenjing Tian and Yingfeng Tu*“A fullerene dyad with a tri(octyloxy)benzene moiety induced efficient nanoscale active layer for the poly(3-hexylthiophene)-based bulk heterojunction solar cell applications” Chemical Communication,2013, 49, 4917-4919.
41. Yujin Chen, Chao Li, Pan Zhang, Yaowen Li,* Xiaoming Yang, Liwei Chen, Yingfeng Tu,* “Solution-Processable Tetrazine and Oligothiophene Based Linear A-D-A Small Molecules: Synthesis, Hierarchical Structure and Photovoltaic Properties” Organic Electronics, 2013, 14, 1424-1434.
42. Lijun Ma, Xiaoming Yang, Lingfeng Gao, Min Lu, Chengxin Guo, Yaowen Li, Yingfeng Tu,* Xiulin Zhu “Synthesis and characterization of polymer grafted graphene oxide sheets using a Ce(IV)/HNO3 redox system in an aqueous solution” Carbon, 2013, 269-276.
43. Jianying Chen, Weichun Huang, Qiaozhen Xu, Yingfeng Tu,* Xiulin Zhu,* Erqiang Chen* “PBT-b-PEO-b-PBT triblock copolymers: synthesis, characterization and double-crystalline properties”Polymer, 2013, 54, 6725-6731.
44. Yaowen Li, Liwei Chen, Yujin Chen, Chao Li, Pan Zhang, Lingfeng Gao, Xiaoming Yang, Yingfeng Tu,* Xiulin Zhu “Conjugated moiety effect on blend film phase separation and photovoltaic properties of benzo[1,2-b:4,5-b0]dithiophene-containing coplanar donor–acceptor copolymers” Solar Energy Materials & Solar Cells, 2013, 108, 136-145.
45. Pan Zhang, Chao Li, Yue Zhao, Yaowen Li,* Yingfeng Tu* “Controlling Morphology of Active Layer by Tuning Coplanarity of the Centrality in Acceptor-Donor-Acceptor Small Molecules for Photovoltaic Application” Chinese Journal of Chemistry, 2013, 31, 1439-1448.
46. Hao-Jan Sun, Yingfeng Tu,* Chien-Lung Wang, Ryan M. Van Horn, Chi-Chun Tsai, Matthew J. Graham, Bin Sun, Bernard Lotz, Wen-Bin Zhang* and Stephen Z. D. Cheng* “Hierarchical structure and polymorphism of a sphere-cubic shape amphiphile based on a polyhedral oligomeric silsesquioxane-[60]fullerene conjugate ” Journal of Materials Chemistry, 2011, 21, 14240-14247.
47. Xiaoming Yang, Lijun Ma, Sheng Wang, Yaowen Li, Yingfeng Tu,* Xiulin Zhu “Clicking graphite oxide sheets with well-defined polystyrenes: A new Strategy to control the layer thickness” Polymer, 2011, 52, 3046-3052.
48. Yaowen Li, Yujin Chen, Xing Liu, Zhong Wang, Xiaoming Yang, Yingfeng Tu,* and Xiulin Zhu “Controlling Blend Film Morphology by Varying Alkyl Side Chain in Highly Coplanar Donor-Acceptor Copolymers for Photovoltaic Application” Macromolecules, 2011, 44, 6370-6381.
49. Yingfeng Tu,* Zhenping Cheng, Zhengbiao Zhang, Jian Zhu, Wei Zhang, Nianchen Zhou, Peihong Ni, Xiulin Zhu* “Mechanism Study and Molecular Design in Controlled/“Living” Radical Polymerization” Science China-Chemistry, 2010, 53, 1605-1619.
50. Yingfeng Tu, Matthew J. Graham, Ryan M. Van Horn, Erqian Chen, Xinhe Fan, Xiaofang Chen, Qifeng Zhou,* Xinhua Wan,* Frank W. Harris, Stephen ZD. Cheng* “Controlled organization of self-assembled rod-coil block copolymer micelles” Polymer,2009, 50, 5170-5174.
51. Yingfeng Tu, XinhuaWan, Hailiang Zhang, Xinhe Fan, Dongning Lu, Xiaofang Chen, Qifeng Zhou* “Self-assembly of rod-coil diblock copolymers influence of the rod length” Chinese Journal of Polymer Science,2003, 21, 569-573.
52. Yingfeng Tu, XinhuaWan, Hailiang Zhang, Xinhe Fan, Xiaofang Chen, Qifeng Zhou,* Kinchiu Chau “Self-assembled nanostructures of rod-coil diblock copolymers with different rod length” Macromolecules, 2003, 36, 6565-6569.
53. Yingfeng Tu, Xinhua Wan, Dong Zhang, Qifeng Zhou, Chi Wu* “Self-assembled nanostructure of a novel coil-rod diblock copolymer in dilute solution” Journal of the American Chemical Society, 2000, 122, 10201-10205.
(更新时间:2020年4月20日)