 | 姓名：曾小庆 职称：教授、博士生导师 部门：化学学院 联系方式： Email: xqzeng@suda.edu.cn 课题组网站 |
学历及学术经历： 1979年8月出生于湖北公安县。2002年毕业于武汉大学环境化学系，获学士学位；2007年毕业于中国科学院北京化学研究所，分子动态与稳态结构国家重点实验室，获博士学位，导师王殿勋教授；2008年加拿大New Brunswick大学无机化学系博士后；2009年获德国洪堡奖学金(Alexander von Humboldt Stiftung)在Bergische Universitaet Wuppertal著名氟化学家Helge Willner教授课题组从事含氟小分子光谱探测与表征研究；2011年获德国科学基金会(DFG)独立项目资助。2013年受聘于18新利体育
材化部，物理化学研究所特聘教授，博士生导师。2014年获国家自然科学基金优秀青年基金。 迄今为止，已在国际核心期刊上发表署名论文80余篇，其中近一半为第一作者。自2009年起，以第一或通讯作者接连在Angew. Chem. Int. Ed. (8篇)，J. Am. Chem. Soc. (2篇), Chem. Eur. J.，Chem. Comm.，Inorg. Chem. 等权威化学期刊发表多篇研究论文，其中发表在Angew. Chem. Int. Ed.上的论文屡次被选为VIP、hotpaper、或封面文章，并多次被国际同行以highlight的形式在Angew. Chem. Int. Ed.上撰写全文评论，在小分子与自由基研究领域建立了独特的研究体系与方法。目前主持国家自然科学基金优秀青年基金、自然科学基金面上项目一项。 研究领域： 研究方向主要包括：教科书式原型小分子的低温合成、分离与表征；亚稳态含能化合物的合成、分子结构与构象以及分解反应；主族元素多键化合物的低温合成与光化学反应；关键自由基反应中间体的产生、光谱捕捉、结构、反应和相关机理的实验与理论探索；新型稳定α-oxo氮烯双自由基的结构与反应；以及稳定自由基在介质中的物理化学行为研究。 课题组网站：http://web.suda.edu.cn/xqzeng/index.html 近五年代表性论文： [1] Zeng, X. Q.;* Li, H. M.; Sun, H. L.; Beckers, H;* Willner, H.; Schaefer III,H. F.* SN2P2: A neutral five-membered sulfur-pnictogen(III) ring. Angew. Chem. Int. Ed.2014, DOI: 10.1002/anie.201409868. [2] Zeng, X. Q.;* Antognini, A. F.; Beckers, H;* Willner, H. Isomers of disulfur dinitride, S2N2. Angew. Chem. Int. Ed. 2014, DOI: 10.1002/anie.201407538. [3] Zeng, X. Q.;* Beckers, H.;* Willner, H.; Neuhaus, P.; Grote, D.; Sander, W. Photochemistry of matrix isolated trifluoromethylsulfonyl azide, CF3SO2N3. J. Phys. Chem. A 2014, DOI: 10.1021/jp506243s. [4] Zeng, X. Q.;* Beckers, H.; Seifert, J.; Banert, K.* The photochemical and thermal decomposition of azidoacetylene in the gas phase, solid matrix, and solutions. Eur.J. Org. Chem. 2014, 4077–4082. [5] Zeng, X. Q.;* Beckers, H.;* Willner, H. The iminyl radical O2SN. Angew. Chem. Int. Ed. 2013, 52, 7981–7984. [6] Zeng, X. Q.;* Beckers, H.;*Willner, H. The novel iminyl radical O2SN. Angew. Chem. Int. Ed. 2013, DOI: 10.1002/anie.201302968. [7] Zeng, X. Q.;* Beckers, H.;* Willner, H. Thermally persistent fluorosulfonyl nitrene and unexpected formation of fluorosulfonyl radical. J. Am. Chem. Soc. 2013, 135, 2096–2099. [8] Zeng, X. Q.;* Bernhardt, E.; Beckers, H.;* Banert, K.; Hagedorn, M.; Liu, H. Formyl azide: properties and solid-state structure. Angew. Chem. Int. Ed.2013, 52,3503–3506. Hot paper. [9] Zeng, X. Q.;* Beckers, H.; Willner, H.; Stanton, J.F.* Fascinating diazirinone (N2CO), a violet gas. Eur. J. Inorg. Chem. 2012,3403–3409.Front cover. [10] Zeng, X.Q.;* Beckers, H.; Willner, H.; Francisco, J. S.* Experimental observation of the 16-electron SPN, SNP, and cyclic PSN. Angew. Chem. Int. Ed. 2012, 51,3334–3339. Inside cover; highlighted as “OPN and SPN: Small molecules with great potential”by Angew. Chem. Int. Ed. 2012, 51, 5541–5542. [11] Zeng, X. Q.; Beckers, H.;* Neuhaus, P.; Grote, D.; Sander, W. Elusive fluoro sulfinyl nitrite produced by photolysis of matrix-isolated FS(O)2N. Z. Anorg. Allg. Chem. 2012, 638, 526–533. [12] Zeng, X. Q.; Beckers, H.;* Willner, H. Elusive O=PºN, a rare example of phosphorus σ2λ5-coordination. J. Am. Chem. Soc. 2011, 133, 20696–20699.JACS spotlight;highlighted as “OPN and SPN: Small molecules with great potential”by Angew. Chem. Int. Ed. 2012, 51, 5541–5542. [13] Zeng, X.Q.; Beckers, H.;* Willner, H.;* Stanton, J. F. Elusive diazirinone, N2CO. Angew. Chem. Int. Ed.2011, 50, 1720–1723. Very Important Paper (VIP); highlighted as “The demise and revival of diazirinone”by Angew. Chem. Int. Ed. 2011, 50,2677–2678. [14] Zeng, X.Q.; Beckers, H.;* Willner, H.* Matrix isolation of two isomers of N4CO. Angew. Chem. Int. Ed.2011, 50, 482–485. Highlighted by Angew. Chem. Int. Ed. 2011, 50, 2677–2678. [15] Zeng, X. Q.; Beckers, H.;* Willner, H.;* Grote, D.; Sander, W. The missing link: Triplet fluorocarbonyl nitrene FC(O)N. Chem. Eur. J.2011, 17,3977–3984. [16] Zeng, X. Q.;* Beckers, H.; Bernhardt, E.; Willner, H. Synthesis and characterization of sulfuryl diazide, O2S(N3)2. Inorg.Chem. 2011, 50, 8679–8684. [17] Zeng, X.Q.;* Bernhardt, E.; Beckers, H.; Willner, H. Synthesis and characterization of the phosphorus triazides OP(N3)3 and SP(N3)3. Inorg. Chem. 2011, 50, 11235–11241. [18] Zeng, X. Q.; Gerken,M.;* Beckers, H.; Willner, H.* Synthesis and characterization of carbonyl diazide, OC(N3)2. Inorg. Chem. 2010, 49,9694–9699. Highlighted as “Explosive carbonyl diazide safely made” by C&EN 2010, 11, 34, and Angew. Chem. Int. Ed. 2011, 50, 2677–2678. [19] Zeng, X. Q.; Gerken, M.; Beckers, H.; Willner,H.* Spectroscopic and structural studies of difluorophosphoryl azide, difluoro phosphoryl isocyanate, and difluorophosphoric acid anhydride. Inorg. Chem.2010, 49, 3002–3010. [20] Zeng, X. Q.; Beckers, H.; Willner, H.;* Berger, R. J. F.; Hayes, S. A.;Mitzel, N. Structure and conformational properties of difluoro(azido)phosphane. Eur.J. Inorg. Chem. 2011, 895–905. [21] Zeng, X. Q.;Gerken, M.;*Beckers, H.; Willner, H. Anomeric effects in sulfonyl compounds: an experimental and computational study of fluorosulfonyl azide, FSO2N3, and trifluoromethylsulfonyl azide, CF3SO2N3. J. Phys. Chem. A2010, 114,7624–7630. [21] Zeng, X. Q.;Beckers, H.;Willner, H.;* Lehmann, C. W. Bis(methanesulfonyl) peroxide: Spectroscopic, structural, and thermal properties Z. Anorg. Allg. Chem.2010, 636, 2447–2453. [22] Zeng, X. Q.; Beckers, H.; Willner, H.* Difluoro-λ5-phosphinonitrile F2P≡N: matrix isolation and photoisomerization into FP=NF. Angew. Chem. Int. Ed.2009, 48, 4828–4831. Very Important Paper (VIP); highlighted as “Stabilized transient R2PN species” by Angew. Chem. Int. Ed. 2013, 52, 3068–3070. [23] Zeng, X. Q.; Beckers, H.; Willner, H.;* Neuhaus,P.; Grote, D.; Sander, W. Difluoro phosphoryl nitrene, F2P(O)N: matrix isolation and unexpected rearrangement to F2PNO. Chem. Eur. J.2009, 15,13466–13473. [24] Zeng, X. Q.; Beckers, H.; Willner, H.* Photoisomerization of matrix isolated F2CS into cis and trans FCSF. Chem. Comm. 2009, 5162–5164. | |
