汪顺义

姓名:汪顺义 (WANG SHUN-YI)

职称:教授、博士生导师



联系方式:
Tel: 15962208862


1998.9-2002.6 18新利体育 化学化工学院 学士

(导师:纪顺俊教授)

2002.9-2007.6 18新利体育 化学化工学院 博士

(导师:纪顺俊教授)

2005.12-2006.12 新加坡南洋理工大学助理研究员

(Research Associate, 新加坡科学院院士、马来西亚科学

院院士、中国千人计 划 Prof. Teck-Peng Loh)

2007.8-2011.2 新加坡南洋理工大学博士后研究员

(Research Fellow, 新加坡科学院院士、马来西亚科学院

院士、中国千人计划 Prof. Teck-Peng Loh)

2011.3-2011.12 德国慕尼黑大学博士后研究员

(Research Fellow, 德国、法国、巴伐利亚科学院院士 Prof. Paul Knochel)

2012.1-2015.06 18新利体育 材料与化学化工学部副教授

2015.06-至今 18新利体育 材料与化学化工学部教授


学术经历:2003年至今,在Nature Commun., Chem. Sci., ACS Catal., Org. Lett., Org.Chem. Front.,Chem. Commun., Adv. Synth. Catal., Chem. Eur. J., J. Org. Chem.等期刊上以第一作者、通讯联系人发表论文140余篇。目前完成国家自然科学基金面上项目2项、国家自然科学基金应急项目1项、江苏省教育厅重大项目1项、国家自然科学基金青年基金1项、江苏省自然科学基金青年基金1项、江苏省有机合成重点实验室开放基金1项。

获奖: 2006-2007年度苏州市自然科学论文一等奖;2007年18新利体育 优秀博士论文、2008年江苏省优秀博士论文、2009年全国百篇优秀博士论文提名奖;2010年第六届亚欧金属促进反应会议优秀墙报奖;作为主要完成人参与的项目“功能性有机分子的合成、性质及应用研究”获得2010年中国石油和化学工业协会科技进步二等奖、2013年教育部高等学校18新利备用网站 优秀成果奖(科学技术)自然科学奖二等奖。2018 年获得 Thieme Chemistry Journals Award 2020 年入选18新利体育 仲英青年学者,2021 年入选苏州市工业园区科技创新领军人才,2023 年入选江苏省青蓝工程中青年学术带头人、姑苏创新创业领军人才。

 

教学经历: 担任本科生强化班《Spectroscopic Methods In Organic Chemistry《有机化学实验》等课程的教学任务,2013年18新利体育 第十二届青年教师课堂教学竞赛三等奖。

 

研究领域:有机硫族化学;自由基参与的新反应研究;ADC抗体偶联药物接头;含硫功能新材料。

 

 

代表性论文及参编著作

回国工作后发表的部分论文

1.       Fei Wang, Ying Chen, Weidong Rao, Lutz Ackermann* and Shun-Yi Wang*

Efficient preparation of unsymmetrical disulfides by nickel-catalyzed reductive coupling strategy

Nature Communications2022, 13, 2588.

2.       Ji-Min Cao, Wei-Chen Zhu, Xin-Yu Liu, Weidong Rao, Shu-Su Shen, Dao-peng Sheng, and Shun-Yi Wang*

Simultaneous Preparation of Sulfides/Selenides and Sulfones via Synergistic Nickel-Catalyzed Reductive Coupling and SN2 Reaction

Organic Letters2023, 25, 9207−9212.

3.       Wang Chen, Xin-yu Liu, Daopeng Sheng, Yi-Fan Jiang, Weidong Rao, Shu-Su Shen, Zhao-Ying Yang and Shun-Yi Wang*

Access to disulfides through ligand-controlled nickel-catalyzed dithiosulfonate and alkyl halides

Organic Chemistry Fronttiers2024, 11, doi.org/10.1039/D3QO01868G.

 

4.       Ying Chen, Fei Wang, Bo-Xi Liu, Wei-Dong Rao and Shun-Yi Wang*

A Ni(II)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates

Organic Chemistry Fronttiers2022, 9, 731–736.

 

5.       Fei Wang, Ying Chen, Lutz Ackermann* and Shun-Yi Wang*

Efficient preparation of unsymmetrical alkyl–aryl tellurides via a nickel-catalyzed reductive coupling strategy

Organic Chemistry Fronttiers2022, 9, 3199-3203.

 

6.       Fei Wang, Ying Chen, Weidong Rao, Shu-Su Shen and Shun-Yi Wang*

Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds

Chemical Communications 2022, 58, 1256412567.

 

7.       Bo-Xi Liu, Fei Wang, Ying Chen, Wei-Dong Rao, Shu-Su Shen, and Shun-Yi Wang*

Visible-Light-Promoted Denitrogenative Ortho-selenylation Reaction of benzotriazinones: Synthesis of ortho-selenylated Benzamides, Ebselen Analogs

Organic Chemistry Fronttiers2022, 9, 2418-2423.

 

8.       Yi-Fan Jiang, Wei-Chen Zhu, Xin-Yu Liu, Shi-Yin Tian, Jia-Hui Han, Weidong Rao, Shu-Su Shen, Daopeng Sheng, and Shun-Yi Wang*

Synthesis of 1,3-Dibenzenesulfonylpolysulfane (DBSPS) and Its Application in the Preparation of Aryl Thiosulfonates from Boronic Acids

Organic Letters2023, 25, 17761781.

 

9.       Ping Song, Weidong Rao, Tristram Chivers* and Shun-Yi Wang*

Applications of trisulfide radical anion S3− in organic synthesis

Organic Chemistry Fronttiers2023, 10, 3378-3400.

 

10.   Xin-Yu Liu,Shi-Yin Tian,Yi-Fan Jiang,Weidong Rao, and Shun-Yi Wang*

Visible Light-Triggered Sulfonylation/aryl migration/desulfonylation and C-S/Se Bond Formation Reaction: 1,2,4-Trifunctionalization of Butenyl Benzothiazole Sulfone with Thiosulfonate/Selenosulfonates

Organic Letters2021, 23, 8246−8251.

 

 

11.   Fei Wang and Shun-Yi Wang*

Visible-light-promoted cross-coupling reaction of hypervalent bis-catecholato silicon compounds with selenosulfonates or thiosulfonates

Organic Chemistry Fronttiers2021, 8, 1976-1982.

 

12.   Jing-Jing Ai, Bei-Bei Liu, Jian Li, Fei Wang, Cheng-Mi Huang, Weidong Rao, and Shun-Yi Wang*

Fe−S Catalyst Generated In Situ from Fe(III)- and S3−-Promoted Aerobic Oxidation of Terminal Alkenes

Organic Letters2021, 23, 4705-4709.

 

13.   Lin Xu, Pei Xu, Yi-Ming Zhu, Weidong Rao and Shun-Yi Wang*

NaI/TBHP-promoted reaction of indole-2-thiones with arylsulfonyl hydrazides: construction of achiral axial 3,3’-biindole-2,2’-dibenzenesulfonothioate derivatives

Organic Chemistry Fronttiers2021, 8, 5383-5388.

 

14.   Cheng-Mi Huang, Jian Li, Jing-Jing Ai, Xin-Yu Liu, Weidong Rao, and Shun-Yi Wang*

Visible-Light-Promoted Cross-Coupling Reactions of Aryldiazonium Salts with S‑Methyl‑d3 Sulfonothioate or Se-Methyl‑ d3 Selenium Sulfonate: Synthesis of Trideuteromethylated Sulfides, Sulfoxides, and Selenides

Organic Letters2020, 22, 9128-9132.

 

15.   Fei Wang, Bo-Xi Liu, Weidong Rao, and Shun-Yi Wang*

Metal-Free Chemoselective Reaction of Sulfoxonium Ylides and Thiosulfonates: Diverse Synthesis of 1,4-Diketones, Aryl Sulfursulfoxonium Ylides, and β‑Keto Thiosulfones Derivatives

Organic Letters2020, 22, 6600-6604.

 

16.   Jian Li, Xin-Er Yang, Shan-Le Wang, Long-Long Zhang, Xiao-Zhou Zhou, Shun-Yi Wang,* and Shun-Jun Ji*

Visible-Light-Promoted Cross-Coupling Reactions of 4‑Alkyl-1,4-dihydropyridines with Thiosulfonate or Selenium Sulfonate: A Unified Approach to Sulfides, Selenides, and Sulfoxides

Organic Letters2020, 22, 4908-4913.

 

 

17.   Jing-Hao Li, Qi Huang, Weidong Rao, Shun-Yi Wang,* and Shun-Jun Ji*

Trisulfur Radical Anion (S3•−) Involved Sulfur Insertion Reaction of 1,3-Enynes: Sulfide Sources Control Chemoselective Synthesis of 2,3,5-trisubstituted Thiophenes and 3-thienyl Disulfides

Chemical Communications 2019, 55, 7808—7811.                

18.   Can Liu,Yi Fang, Shun-Yi Wang,* and Shun-Jun Ji*

RhCl3×3H2O-Catalyzed Ligand-Enabled Highly Regioselective Thiolation of Acrylic Acids

ACS Catalysis2019, 9, 8910−8915.                    

19.   Yi Fang, Can Liu, Weidong Rao, Shun-Yi Wang* and Shun-Jun Ji*

Metal-free Synthesis of N-(Carboselenoate) benzimidazolones by Cascade Cyclization of ortho-Diisocyanoarenes and Selenosulfonates

Organic Letters 2019, 21, 7687-7691.

20.   Jian Li,Weidong Rao,Shun-Yi Wang,*, and Shun-Jun Ji*

Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction of gem-Difluoroalkenes with Thiosulfonate or Selenium Sulfonate

The Journal of Organic Chemistry 2019, 84, 11542-11552.

21.   Jian Li, Shun-Yi Wang,* and Shun-Jun Ji*

Nickel-Catalyzed Thiolation/ and Selenylation of Cycloketone Oxime Esters with Thiosulfonate or Selenium sulfonate

The Journal of Organic Chemistry 2019, 84, 16147-16156. 

22.   Fei Wang, Pei Xu, Bei-Bei Liu, Shun-Yi Wang* and Shun-Jun Ji*

Pd-Catalyzed Multicomponent Reaction of Sulfonyl azide, Primary amines and Methyl α-lsocyanoacetates: Highly Efficient Synthesis of Tetrasubstituted Imidazolidone Derivatives

Organic Chemistry Frontiers 2019, 6, 3754-3758.

23.   Pei Xu, Yi-Ming Zhu, Fei Wang, Shun-Yi Wang,* and Shun-Jun Ji* 

Mn(III)-Mediated Cascade Cyclization of 3-Isocyano-[1,1'-biphenyl]-2-carbonitrile with Arylboronic Acid: Construction of Pyrrolopyridine Derivatives

Organic Letters 2019, 21, 683-686.  

 

24.   Nan Jiang,Yi Fang,Yue Fang,Shun-Yi Wang* and Shun-Jun Ji*

Iodine Promoted One Pot reaction of pyridin-2-amine with Arylmethyl Ketone and Selenosulfonate: Synthesis of 3-(Alkylselanyl)-2-arylimidazo[1,2-a]pyridine Under Transition-metal Free Conditions

Organic Chemistry Frontiers 2019, 6, 654-659.      

25.   Yi Fang, Can Liu, Fei Wang, Rao Ding, Shun-Yi Wang* and Shun-Jun Ji*

Radical-chain reaction of Isocyanides with Selenosulfonates and Water: Facile Synthesis of Selenocarbamates Under Metal-free Conditions

Organic Chemistry Frontiers 2019, 6, 660-663.

26.    

27.   Yi Fang, Torben Rogge, Lutz Ackermann, Shun-Yi Wang,* and Shun-Jun Ji*

Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides

Nature Communications 2018, 9, 2240.                      (SCI  12.353)

 

28.   Rong Zhang, Zheng-Yang Gu, Shun-Yi Wang,* and Shun-Jun Ji*

Co(II)/Ag(I) Synergistically Catalyzed Mono-insertion Reaction of Isocyanide to Terminal Alkynes with H2O: Synthesis of Alkynamides Derivatives

Organic Letters 2018, 20, DOI: 10.1021/acs.orglett.8b02516

 

29.   Jing-Hao Li, Qi Huang,Shun-Yi Wang,* and Shun-Jun Ji*

Trisulfur Radical Anion (S3•−) Involved [1+2+2] and [1+3+1] Cycloaddition with Aromatic Alkynes: Synthesis of Tetraphenylthiophene and 2-Benzylidenetetrahydrothiophene Derivatives

Organic Letters 2018, 20, 4704-4708.

 

30.   Huan Liu, Yi Fang, Shun-Yi Wang,* and Shun-Jun Ji*

TEMPO-catalyzed aerobic oxidative selenium insertion reaction:  synthesis of 3-selenylindole derivatives by multicomponent reaction of isocyanides, selenium powder, amines and indoles under transition metal-free conditions

Organic Letters 2018, 20, 930-933.

 

31.   Fei Wang, Pei Xu,Shun-Yi Wang,* and Shun-Jun Ji*

Cu(II)/Ag(I)-Catalyzed Cascade Reaction of Sulfonylhydrazone with Anthranils: Synthesis of 2-Aryl-3-sulfonyl Substituted Quinoline Derivatives

Organic Letters 2018, 20, 2204-2207.

 

32.   Zheng-Yang Gu, Rong Zhang, Shun-Yi Wang,* and Shun-Jun Ji*

Cobalt(II)-Catalyzed Bis-isocyanides Insertion Reactions with Boric acids and Sulfonyl Azides via Nitrene Radical Coupling

Chinese Journal of Chemistry2018, 36, 1011-1016.

 

33.   Zheng-Yang Gu,Yuan Liu,Fei Wang,Xiaoguang Bao,*Shun-Yi Wang,*and Shun-Jun Ji*

Cobalt(II)-Catalyzed Synthesis of Sulfonyl Guanidines via Nitrene Radical Coupling with Isonitriles: A Combined Experimental and Computational Study

ACS Catalysis2017, 7, 3893−3899.                     

 

 

 




34.   Yi Fang, Zheng-Lin Zhu, Pei Xu, Shun-Yi Wang,* and Shun-Jun Ji*

Aerobic Radical-Cascade Cycloaddition of Isocyanides, Selenium and Imidamides: Facile Access to 1,2,4-Selenadiazoles under Metal-Free Conditions, Green Chemistry 2017, 19, 1613-1618.  

 

35.   Pei Xu, Fei Wang, Tian-Qi Wei, Ling Yin, Shun-Yi Wang,* and Shun-Jun Ji*

Palladium-catalyzed Incorporation of Two C1 Building Blocks: The Reaction of Atmospheric CO2 and Isocyanides with 2-Iodoanilines Leading to an Synthesis of Quinazoline-2,4(1H,3H)-diones

Organic Letters 2017, 19, 4484-4487.

 

36.   Zheng-Yang Gu, Jia-Jia Cao, Shun-Yi Wang,* and Shun-Jun Ji*The Involvement of the Trisulfur Radical Anion in Electron-Catalyzed Sulfur Insertion Reactions: Facile Synthesis of Benzothiazine Derivatives under Transition Metal-free Conditions, Chemical Science2016, 7, 4067-4072.    

 

37.   Zheng-Yang Gu, Cheng-Guo Liu, Shun-Yi Wang,* and Shun-Jun Ji* Pd-Catalyzed Intramolecular Heck Reaction, C(sp2)−H Activation, 1,4-Pd Migration and Aminopalladation: Chemoselective Synthesis of Dihydroindeno[1,2,3-kl]acridines and 3-Arylindoles

Organic Letters 2016, 18, 2379-2382.                     

 

38.   Zhong-Jian Cai, Fang-Hui Li, Shun-Yi Wang* and Shun-Jun Ji*

Palladium-Catalyzed Cascade Arene/Alkyne Annulation: Synthesis of Fluorene-Benzoxazine Derivatives

Organic Letters 2016, 18, 4810-4813.   

 

39.   Hui-Wen Bai, Zhong-Jian Cai, Shun-Yi Wang,* and Shun-Jun Ji*

Aerobic Oxidative Cycloaddition of α-Chlorotosylhydrazones with Arylamines: General Chemoselective Construction of 1,4-Disubstituted and 1,5-Disubstituted 1,2,3-Triazoles under Metal-free and Azide-free Conditions

Organic Letters 2015, 17, 17, 2898-2901.  

 

40.   Tong-Hao Zhu,Shun-Yi Wang,* Yang-Qing Tao, and Shun-Jun Ji*

Synthesis of Carbodiimides by I2/CHP Mediated Cross Coupling Reaction of Isocyanides withAmines under Metal-free Conditions

Organic Letters 2015, 17, 1974-1977.

 

 

41.   Zheng-Yang Gu, Tong-Hao Zhu,  Jia-Jia Cao, Xiao-Ping Xu, Shun-Yi Wang,* and Shun-Jun Ji*

Palladium-catalyzed Cascade Reactions of Isocyanides with Enaminones: Synthesis of 4-Aminoquinoline Derivatives

ACS Catalysis2014, 4, 49-52. Invited paper: Virtual special issue on cascade catalysis.

 

42.   Jia-Jia Cao, Tong-Hao Zhu, Shun-Yi Wang*, Zheng-Yang Gu, Xiang Wang and Shun-Jun Ji*  tert-Butyl benzoperoxoate (TBPB) Mediated 2-Isocyanobiaryls Insertion with 1,4-Dioxane: Efficient Synthesis of 6-Alkyl Phenathridines via C(sp3)-H/C(sp2)-H Bond Functionalization

Chemical Communications2014, 50, 6439-6442. Front cover picture paper. 英国皇家化学学会RSC2015年“ TOP1%高被引中国作者”论文。

43.   Jia-Jia Cao, Xiang Wang, Shun-Yi Wang*, and Shun-Jun Ji*

Mn(III)-mediated Reactions of 2-Isocyanobiaryl with 1, 3-Dicarbonyl Compounds: Efficient Synthesis of 6-Alkylated and 6-Monofluoro-alkylated Phenanthridines

Chemical Communications2014, 50, 12892-12895.

 

回国工作前发表的部分论文

44.         Shun-Yi Wang,† Ping Song,† Li-Yan Chan and Teck-Peng Loh* Total Synthesis of Phytophora Mating Hormone α1 Org. Lett. 2010, 12, 5166-5169. 

45.         Shun-Yi Wang, Ping Song, Yen-Jin Chin, and Teck-Peng Loh* A General Strategy for the Introduction of Stereogenic Centers Bearing Methyl Group: Total Synthesis of Sex Pheromones Chem.-Asian. J. 2011, 6, 385-388. 

46.         Shun-Yi Wang and Teck-Peng Loh* Cu(I)-Tol-BINAP-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to α,β−Unsaturated Esters Chem. Commun. 2010, 46, 8694-8703. 

47.         Shun-Yi Wang, Ping Song and Teck-Peng Loh* Excess Phosphine Ligand Plays A Critical Role in The Asymmetric CuI-Catalyzed Conjugate Addition of Grignard Reagents to α,β-Unsaturated Esters Adv. Syn. Catal. 2010, 352, 3185-3189. 

48.         Shun-Yi Wang, Chin Yen-Jin, Teck-Peng Loh* Synthesis of C13-C23 fragment of Iriomoteolide-1a. Synthesis 2009, 3557-3564.  

49.         Shun-Yi Wang, Lum, Tze-Keong, Shun-Jun Ji, Teck-Peng Loh* Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to alpha,beta-unsaturated esters Adv. Syn. Catal. 2008, 350, 673-677.

50.         Shun-Yi Wang, Shun-Jun Ji*, Teck-Peng Loh* Cu(I) Tol-BINAP-Catalyzed Enantioselective Michael Reactions of Grignard reagents and Unsaturated Esters J. Am. Chem. Soc. 2007, 129, 276-277.