姓名:汪顺义 (WANG SHUN-YI) 职称:教授、博士生导师 联系方式: Email:shunyi@suda.edu.cn Tel: 15962208862 | |
1998.9-2002.6 18新利体育 化学化工学院 学士
(导师:纪顺俊教授)
2002.9-2007.6 18新利体育 化学化工学院 博士
(导师:纪顺俊教授)
2005.12-2006.12 新加坡南洋理工大学助理研究员
(Research Associate, 新加坡科学院院士、马来西亚科学
院院士、中国千人计 划 Prof. Teck-Peng Loh)
2007.8-2011.2 新加坡南洋理工大学博士后研究员
(Research Fellow, 新加坡科学院院士、马来西亚科学院
院士、中国千人计划 Prof. Teck-Peng Loh)
2011.3-2011.12 德国慕尼黑大学博士后研究员
(Research Fellow, 德国、法国、巴伐利亚科学院院士 Prof. Paul Knochel)
2012.1-2015.06 18新利体育 材料与化学化工学部副教授
2015.06-至今 18新利体育 材料与化学化工学部教授
学术经历:2003年至今,在Nature Commun., Chem. Sci., ACS Catal., Org. Lett., Org.Chem. Front.,Chem. Commun., Adv. Synth. Catal., Chem. Eur. J., J. Org. Chem.等期刊上以第一作者、通讯联系人发表论文140余篇。目前完成国家自然科学基金面上项目2项、国家自然科学基金应急项目1项、江苏省教育厅重大项目1项、国家自然科学基金青年基金1项、江苏省自然科学基金青年基金1项、江苏省有机合成重点实验室开放基金1项。
获奖: 2006年-2007年度苏州市自然科学论文一等奖;2007年18新利体育 优秀博士论文、2008年江苏省优秀博士论文、2009年全国百篇优秀博士论文提名奖;2010年第六届亚欧金属促进反应会议优秀墙报奖;作为主要完成人参与的项目“功能性有机分子的合成、性质及应用研究”获得2010年中国石油和化学工业协会科技进步二等奖、2013年教育部高等学校18新利备用网站 优秀成果奖(科学技术)自然科学奖二等奖。2018 年获得 Thieme Chemistry Journals Award ,2020 年入选18新利体育 仲英青年学者,2021 年入选苏州市工业园区科技创新领军人才,2023 年入选江苏省青蓝工程中青年学术带头人、姑苏创新创业领军人才。
教学经历: 担任本科生强化班《Spectroscopic Methods In Organic Chemistry》,《有机化学实验》等课程的教学任务,2013年18新利体育 第十二届青年教师课堂教学竞赛三等奖。
研究领域:有机硫族化学;自由基参与的新反应研究;ADC抗体偶联药物接头;含硫功能新材料。
代表性论文及参编著作
回国工作后发表的部分论文
1. Fei Wang, Ying Chen, Weidong Rao, Lutz Ackermann* and Shun-Yi Wang*
Efficient preparation of unsymmetrical disulfides by nickel-catalyzed reductive coupling strategy
Nature Communications2022, 13, 2588.
2. Ji-Min Cao, Wei-Chen Zhu, Xin-Yu Liu, Weidong Rao, Shu-Su Shen, Dao-peng Sheng, and Shun-Yi Wang*
Simultaneous Preparation of Sulfides/Selenides and Sulfones via Synergistic Nickel-Catalyzed Reductive Coupling and SN2 Reaction
Organic Letters2023, 25, 9207−9212.
3. Wang Chen, Xin-yu Liu, Daopeng Sheng, Yi-Fan Jiang, Weidong Rao, Shu-Su Shen, Zhao-Ying Yang and Shun-Yi Wang*
Access to disulfides through ligand-controlled nickel-catalyzed dithiosulfonate and alkyl halides
Organic Chemistry Fronttiers2024, 11, doi.org/10.1039/D3QO01868G.
4. Ying Chen, Fei Wang, Bo-Xi Liu, Wei-Dong Rao and Shun-Yi Wang*
A Ni(II)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates
Organic Chemistry Fronttiers2022, 9, 731–736.
5. Fei Wang, Ying Chen, Lutz Ackermann* and Shun-Yi Wang*
Efficient preparation of unsymmetrical alkyl–aryl tellurides via a nickel-catalyzed reductive coupling strategy
Organic Chemistry Fronttiers2022, 9, 3199-3203.
6. Fei Wang, Ying Chen, Weidong Rao, Shu-Su Shen and Shun-Yi Wang*
Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds
Chemical Communications 2022, 58, 12564–12567.
7. Bo-Xi Liu, Fei Wang, Ying Chen, Wei-Dong Rao, Shu-Su Shen, and Shun-Yi Wang*
Visible-Light-Promoted Denitrogenative Ortho-selenylation Reaction of benzotriazinones: Synthesis of ortho-selenylated Benzamides, Ebselen Analogs
Organic Chemistry Fronttiers2022, 9, 2418-2423.
8. Yi-Fan Jiang, Wei-Chen Zhu, Xin-Yu Liu, Shi-Yin Tian, Jia-Hui Han, Weidong Rao, Shu-Su Shen, Daopeng Sheng, and Shun-Yi Wang*
Synthesis of 1,3-Dibenzenesulfonylpolysulfane (DBSPS) and Its Application in the Preparation of Aryl Thiosulfonates from Boronic Acids
Organic Letters2023, 25, 1776−1781.
9. Ping Song, Weidong Rao, Tristram Chivers* and Shun-Yi Wang*
Applications of trisulfide radical anion S3•− in organic synthesis
Organic Chemistry Fronttiers2023, 10, 3378-3400.
10. Xin-Yu Liu,Shi-Yin Tian,Yi-Fan Jiang,Weidong Rao, and Shun-Yi Wang*
Visible Light-Triggered Sulfonylation/aryl migration/desulfonylation and C-S/Se Bond Formation Reaction: 1,2,4-Trifunctionalization of Butenyl Benzothiazole Sulfone with Thiosulfonate/Selenosulfonates
Organic Letters2021, 23, 8246−8251.
11. Fei Wang and Shun-Yi Wang*
Visible-light-promoted cross-coupling reaction of hypervalent bis-catecholato silicon compounds with selenosulfonates or thiosulfonates
Organic Chemistry Fronttiers2021, 8, 1976-1982.
12. Jing-Jing Ai, Bei-Bei Liu, Jian Li, Fei Wang, Cheng-Mi Huang, Weidong Rao, and Shun-Yi Wang*
Fe−S Catalyst Generated In Situ from Fe(III)- and S3•−-Promoted Aerobic Oxidation of Terminal Alkenes
Organic Letters2021, 23, 4705-4709.
13. Lin Xu, Pei Xu, Yi-Ming Zhu, Weidong Rao and Shun-Yi Wang*
NaI/TBHP-promoted reaction of indole-2-thiones with arylsulfonyl hydrazides: construction of achiral axial 3,3’-biindole-2,2’-dibenzenesulfonothioate derivatives
Organic Chemistry Fronttiers2021, 8, 5383-5388.
14. Cheng-Mi Huang, Jian Li, Jing-Jing Ai, Xin-Yu Liu, Weidong Rao, and Shun-Yi Wang*
Visible-Light-Promoted Cross-Coupling Reactions of Aryldiazonium Salts with S‑Methyl‑d3 Sulfonothioate or Se-Methyl‑ d3 Selenium Sulfonate: Synthesis of Trideuteromethylated Sulfides, Sulfoxides, and Selenides
Organic Letters2020, 22, 9128-9132.
15. Fei Wang, Bo-Xi Liu, Weidong Rao, and Shun-Yi Wang*
Metal-Free Chemoselective Reaction of Sulfoxonium Ylides and Thiosulfonates: Diverse Synthesis of 1,4-Diketones, Aryl Sulfursulfoxonium Ylides, and β‑Keto Thiosulfones Derivatives
Organic Letters2020, 22, 6600-6604.
16. Jian Li, Xin-Er Yang, Shan-Le Wang, Long-Long Zhang, Xiao-Zhou Zhou, Shun-Yi Wang,* and Shun-Jun Ji*
Visible-Light-Promoted Cross-Coupling Reactions of 4‑Alkyl-1,4-dihydropyridines with Thiosulfonate or Selenium Sulfonate: A Unified Approach to Sulfides, Selenides, and Sulfoxides
Organic Letters2020, 22, 4908-4913.
17. Jing-Hao Li, Qi Huang, Weidong Rao, Shun-Yi Wang,* and Shun-Jun Ji*
Trisulfur Radical Anion (S3•−) Involved Sulfur Insertion Reaction of 1,3-Enynes: Sulfide Sources Control Chemoselective Synthesis of 2,3,5-trisubstituted Thiophenes and 3-thienyl Disulfides
Chemical Communications 2019, 55, 7808—7811.
18. Can Liu,Yi Fang, Shun-Yi Wang,* and Shun-Jun Ji*
RhCl3×3H2O-Catalyzed Ligand-Enabled Highly Regioselective Thiolation of Acrylic Acids
ACS Catalysis2019, 9, 8910−8915.
19. Yi Fang, Can Liu, Weidong Rao, Shun-Yi Wang* and Shun-Jun Ji*
Metal-free Synthesis of N-(Carboselenoate) benzimidazolones by Cascade Cyclization of ortho-Diisocyanoarenes and Selenosulfonates
Organic Letters 2019, 21, 7687-7691.
20. Jian Li,Weidong Rao,Shun-Yi Wang,*, and Shun-Jun Ji*
Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction of gem-Difluoroalkenes with Thiosulfonate or Selenium Sulfonate
The Journal of Organic Chemistry 2019, 84, 11542-11552.
21. Jian Li, Shun-Yi Wang,* and Shun-Jun Ji*
Nickel-Catalyzed Thiolation/ and Selenylation of Cycloketone Oxime Esters with Thiosulfonate or Selenium sulfonate
The Journal of Organic Chemistry 2019, 84, 16147-16156.
22. Fei Wang, Pei Xu, Bei-Bei Liu, Shun-Yi Wang* and Shun-Jun Ji*
Pd-Catalyzed Multicomponent Reaction of Sulfonyl azide, Primary amines and Methyl α-lsocyanoacetates: Highly Efficient Synthesis of Tetrasubstituted Imidazolidone Derivatives
Organic Chemistry Frontiers 2019, 6, 3754-3758.
23. Pei Xu, Yi-Ming Zhu, Fei Wang, Shun-Yi Wang,* and Shun-Jun Ji*
Mn(III)-Mediated Cascade Cyclization of 3-Isocyano-[1,1'-biphenyl]-2-carbonitrile with Arylboronic Acid: Construction of Pyrrolopyridine Derivatives
Organic Letters 2019, 21, 683-686.
24. Nan Jiang,Yi Fang,Yue Fang,Shun-Yi Wang* and Shun-Jun Ji*
Iodine Promoted One Pot reaction of pyridin-2-amine with Arylmethyl Ketone and Selenosulfonate: Synthesis of 3-(Alkylselanyl)-2-arylimidazo[1,2-a]pyridine Under Transition-metal Free Conditions
Organic Chemistry Frontiers 2019, 6, 654-659.
25. Yi Fang, Can Liu, Fei Wang, Rao Ding, Shun-Yi Wang* and Shun-Jun Ji*
Radical-chain reaction of Isocyanides with Selenosulfonates and Water: Facile Synthesis of Selenocarbamates Under Metal-free Conditions
Organic Chemistry Frontiers 2019, 6, 660-663.
26.
27. Yi Fang, Torben Rogge, Lutz Ackermann, Shun-Yi Wang,* and Shun-Jun Ji*
Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides
Nature Communications 2018, 9, 2240. (SCI 12.353)
28. Rong Zhang, Zheng-Yang Gu, Shun-Yi Wang,* and Shun-Jun Ji*
Co(II)/Ag(I) Synergistically Catalyzed Mono-insertion Reaction of Isocyanide to Terminal Alkynes with H2O: Synthesis of Alkynamides Derivatives
Organic Letters 2018, 20, DOI: 10.1021/acs.orglett.8b02516
29. Jing-Hao Li, Qi Huang,Shun-Yi Wang,* and Shun-Jun Ji*
Trisulfur Radical Anion (S3•−) Involved [1+2+2] and [1+3+1] Cycloaddition with Aromatic Alkynes: Synthesis of Tetraphenylthiophene and 2-Benzylidenetetrahydrothiophene Derivatives
Organic Letters 2018, 20, 4704-4708.
30. Huan Liu, Yi Fang, Shun-Yi Wang,* and Shun-Jun Ji*
TEMPO-catalyzed aerobic oxidative selenium insertion reaction: synthesis of 3-selenylindole derivatives by multicomponent reaction of isocyanides, selenium powder, amines and indoles under transition metal-free conditions
Organic Letters 2018, 20, 930-933.
31. Fei Wang, Pei Xu,Shun-Yi Wang,* and Shun-Jun Ji*
Cu(II)/Ag(I)-Catalyzed Cascade Reaction of Sulfonylhydrazone with Anthranils: Synthesis of 2-Aryl-3-sulfonyl Substituted Quinoline Derivatives
Organic Letters 2018, 20, 2204-2207.
32. Zheng-Yang Gu, Rong Zhang, Shun-Yi Wang,* and Shun-Jun Ji*
Cobalt(II)-Catalyzed Bis-isocyanides Insertion Reactions with Boric acids and Sulfonyl Azides via Nitrene Radical Coupling
Chinese Journal of Chemistry2018, 36, 1011-1016.
33. Zheng-Yang Gu,Yuan Liu,Fei Wang,Xiaoguang Bao,*Shun-Yi Wang,*and Shun-Jun Ji*
Cobalt(II)-Catalyzed Synthesis of Sulfonyl Guanidines via Nitrene Radical Coupling with Isonitriles: A Combined Experimental and Computational Study
ACS Catalysis2017, 7, 3893−3899.
34. Yi Fang, Zheng-Lin Zhu, Pei Xu, Shun-Yi Wang,* and Shun-Jun Ji*
Aerobic Radical-Cascade Cycloaddition of Isocyanides, Selenium and Imidamides: Facile Access to 1,2,4-Selenadiazoles under Metal-Free Conditions, Green Chemistry 2017, 19, 1613-1618.
35. Pei Xu, Fei Wang, Tian-Qi Wei, Ling Yin, Shun-Yi Wang,* and Shun-Jun Ji*
Palladium-catalyzed Incorporation of Two C1 Building Blocks: The Reaction of Atmospheric CO2 and Isocyanides with 2-Iodoanilines Leading to an Synthesis of Quinazoline-2,4(1H,3H)-diones
Organic Letters 2017, 19, 4484-4487.
36. Zheng-Yang Gu, Jia-Jia Cao, Shun-Yi Wang,* and Shun-Jun Ji*,The Involvement of the Trisulfur Radical Anion in Electron-Catalyzed Sulfur Insertion Reactions: Facile Synthesis of Benzothiazine Derivatives under Transition Metal-free Conditions, Chemical Science2016, 7, 4067-4072.
37. Zheng-Yang Gu, Cheng-Guo Liu, Shun-Yi Wang,* and Shun-Jun Ji* Pd-Catalyzed Intramolecular Heck Reaction, C(sp2)−H Activation, 1,4-Pd Migration and Aminopalladation: Chemoselective Synthesis of Dihydroindeno[1,2,3-kl]acridines and 3-Arylindoles
Organic Letters 2016, 18, 2379-2382.
38. Zhong-Jian Cai, Fang-Hui Li, Shun-Yi Wang* and Shun-Jun Ji*
Palladium-Catalyzed Cascade Arene/Alkyne Annulation: Synthesis of Fluorene-Benzoxazine Derivatives
Organic Letters 2016, 18, 4810-4813.
39. Hui-Wen Bai, Zhong-Jian Cai, Shun-Yi Wang,* and Shun-Jun Ji*
Aerobic Oxidative Cycloaddition of α-Chlorotosylhydrazones with Arylamines: General Chemoselective Construction of 1,4-Disubstituted and 1,5-Disubstituted 1,2,3-Triazoles under Metal-free and Azide-free Conditions
Organic Letters 2015, 17, 17, 2898-2901.
40. Tong-Hao Zhu,Shun-Yi Wang,* Yang-Qing Tao, and Shun-Jun Ji*
Synthesis of Carbodiimides by I2/CHP Mediated Cross Coupling Reaction of Isocyanides withAmines under Metal-free Conditions
Organic Letters 2015, 17, 1974-1977.
41. Zheng-Yang Gu,‡ Tong-Hao Zhu, ‡ Jia-Jia Cao, Xiao-Ping Xu, Shun-Yi Wang,* and Shun-Jun Ji*
Palladium-catalyzed Cascade Reactions of Isocyanides with Enaminones: Synthesis of 4-Aminoquinoline Derivatives
ACS Catalysis2014, 4, 49-52. Invited paper: Virtual special issue on cascade catalysis.
42. Jia-Jia Cao, Tong-Hao Zhu, Shun-Yi Wang*, Zheng-Yang Gu, Xiang Wang and Shun-Jun Ji* tert-Butyl benzoperoxoate (TBPB) Mediated 2-Isocyanobiaryls Insertion with 1,4-Dioxane: Efficient Synthesis of 6-Alkyl Phenathridines via C(sp3)-H/C(sp2)-H Bond Functionalization
Chemical Communications2014, 50, 6439-6442. Front cover picture paper. 英国皇家化学学会RSC2015年“ TOP1%高被引中国作者”论文。
43. Jia-Jia Cao, Xiang Wang, Shun-Yi Wang*, and Shun-Jun Ji*
Mn(III)-mediated Reactions of 2-Isocyanobiaryl with 1, 3-Dicarbonyl Compounds: Efficient Synthesis of 6-Alkylated and 6-Monofluoro-alkylated Phenanthridines
Chemical Communications2014, 50, 12892-12895.
回国工作前发表的部分论文
44. Shun-Yi Wang,† Ping Song,† Li-Yan Chan and Teck-Peng Loh* Total Synthesis of Phytophora Mating Hormone α1 Org. Lett. 2010, 12, 5166-5169.
45. Shun-Yi Wang, Ping Song, Yen-Jin Chin, and Teck-Peng Loh* A General Strategy for the Introduction of Stereogenic Centers Bearing Methyl Group: Total Synthesis of Sex Pheromones Chem.-Asian. J. 2011, 6, 385-388.
46. Shun-Yi Wang and Teck-Peng Loh* Cu(I)-Tol-BINAP-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to α,β−Unsaturated Esters Chem. Commun. 2010, 46, 8694-8703.
47. Shun-Yi Wang, Ping Song and Teck-Peng Loh* Excess Phosphine Ligand Plays A Critical Role in The Asymmetric CuI-Catalyzed Conjugate Addition of Grignard Reagents to α,β-Unsaturated Esters Adv. Syn. Catal. 2010, 352, 3185-3189.
48. Shun-Yi Wang, Chin Yen-Jin, Teck-Peng Loh* Synthesis of C13-C23 fragment of Iriomoteolide-1a. Synthesis 2009, 3557-3564.
49. Shun-Yi Wang, Lum, Tze-Keong, Shun-Jun Ji, Teck-Peng Loh* Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to alpha,beta-unsaturated esters Adv. Syn. Catal. 2008, 350, 673-677.
50. Shun-Yi Wang, Shun-Jun Ji*, Teck-Peng Loh* Cu(I) Tol-BINAP-Catalyzed Enantioselective Michael Reactions of Grignard reagents and Unsaturated Esters J. Am. Chem. Soc. 2007, 129, 276-277.