吴涛
  姓名:吴涛
  职称:教授、博士生导师

  部门:化学学院
  联系方式:
  
 课题组网站

学历及学术经历:

        19996月毕业于湖北三峡学院(现名三峡大学)师范学院化学系化学教育专业,获理学学士学位;20036月获得汕头大学工业催化专业工学硕士学位;20118月获得美国加州大学河滨分校(University of California, Riverside)无机化学专业理学博士学位。20037月至20068月期间,在汕头大学理学院化学系任教,先后担任助教和讲师之职;20119月至20124月,在加大河滨分校从事博士后研究工作;20126月入职18新利体育 材料与化学化工学部,授特聘教授、博士生导师资格。2011年获得国家优秀自费留学生奖;江苏省创新团队计划引进团队核心成员和苏州市高等院校、科研院所紧缺高层次人才2013年入选江苏省双创计划2014年入选苏州市工业园区金鸡湖双百人才计划2018年入选江苏省第十五批“六大人才高峰”高层次人才。长期从事晶态杂化微孔框架材料和半导体纳米团簇等化学材料领域的基础性研究工作,尤其在构建半导体纳米团簇中精确位点-性能构效关系、实现分立团簇的溶液离散化和催化应用、以及拓展晶态半导体框架材料多功能化应用方面,做出了诸多开创性贡献。目前,已在化学领域系列国际权威期刊发表联合署名学术论文近130篇,共计引用频次7330余次(目前H-index52),其中以第一作者身份在化学综合类Top期刊发表J. Am. Chem. Soc. (5) Angew. Chem. Int. Ed. (3)以独立通讯或第一通讯作者身份在化学综合类Top期刊发表J. Am. Chem. Soc. (5) Angew. Chem. Int. Ed. (2)。曾主持完成国家自然科学基金面上项目1项,现主持国家自然科学基金面上项目2,江苏省杰出青年基金1项。


研究领域:配位化学、无机合成化学、团簇化学、无机有机杂化功能材料

      本课题组致力于晶态无机-有机杂化功能材料的设计、合成及功能化探究等方面的基础性研究,为新型晶态材料的实际应用提供物质基础和技术支持。该研究涉及如下多个领域:无机合成与制备化学、配位化学、团簇化学、光电化学、金属有机框架材料、分子筛多孔材料、半导体材料。目前,主要研究兴趣如下:

(1)新型金属硫族分子团簇或纳米团簇的设计合成和表面官能化

(2)金属硫族簇基开放骨架和基于金属硫族簇基MOFs材料的设计合成

(3)具有半导体特性的类分子筛骨架材料的设计合成和光电性能调控

(4)基于微孔半导体主客体材料的构建及其能量转移和光电子转移机制研究

(5)离散型金属硫族分子团簇的荧光和电化学发光性能研究

(6)多元金属硫族簇基电催化剂的制备及其电催化、光催化性能研究

  

苏大教师个人主页:http://web.suda.edu.cn/wutao

  

Research ID:https://publons.com/researcher/2707340/tao-wu/

  

热诚欢迎有志于科研事业的学子报考本课题组硕士和博士研究生,或申请博士后职位。


通讯作者代表性论文:(*为通讯作者,第一通讯单位均为18新利体育 )

[1] Liu, D. L.++; Fan, X.++; Wang, X.; Hu, D. D.; Xue, C. Z.; Liu, Y.; Wang, Y.; Zhu, X.; Guo, J.; Lin, H. P.*; Li, Y. Y.; Zhong, J.*; Li, D. S.; Bu, X.*; Feng, P.; Wu, T.*Cooperativity by Multi-Metals Confined in Supertetrahedral Sulfide Nanocluster on Enhancing Electrocatalytic Hydrogen Evolution. Chem. Mater. 2019, 31, 553-559. (Front Cover) [++These authors contributed equally to this work]

[2] Lv, J.; Zhang, J. X.; Xue, C. Z.; Hu, D. D.; Wang, X.; Li, D. S.; Wu, T.*Two Penta-Supertetrahedral Cluster-Based Chalcogenide Open Frameworks: Effect of Cluster Spatial Connectivity on Electronic Transport Efficiency.Inorg. Chem. 2019, 58, 3582-3585.

[3] Wang, W.; Wang, X.; Yang, H. J.; Luo, M.; Xue, C. Z.; Lin, Z. E.; Wu, T.* Three-Dimensional Superlattices Based on Unusual Chalcogenide Supertetrahedral TO2-InSnS Nanoclusters. Inorg. Chem.2019, 58, 31-34.

[4] Yang, H. J.++; Zhang, J. X.++; Luo, M.; Wang, W.; Lin, H. P.; Li, Y. Y.; Li, D. S.; Feng, P.; Wu, T.* The Largest Supertetrahedral Oxysulfide Nanocluster and Its Unique Assembly Mode. J. Am. Chem. Soc.2018, 57, 11189-11192. (Inside Cover) [++These authors contributed equally to this work.]

[5] Liu, D. L.; Liu, Y.; Huang, P.; Zhu, C.; Kang, Z. H.; Shu, J.; Chen, M. Z.; Zhu, X.; Guo, J.; Zhuge, L. J.; Bu, X.; Feng, P.*;Wu. T.* Highly Tunable Heterojunctions from Multimetallic Sufide Nanoparticles and Silver Nanowires.Angew. Chem. Int. Ed.2018,57, 5374-5378.

[6] Xu, X. F.++; Wang, W.++; Liu, D. L.; Hu, D. D.; Wu, T.*; Bu, X.; Feng, P.* Pushing up the Size Limit of Metal Chalcogenide Supertetrahedral Nanocluster.J. Am. Chem. Soc.2018, 140, 888-891. [++These authors contributed equally to this work.]

[7] Yang, H. J.; Luo, M.; Wu, Z.; Wang, W.; Xue, C. Z.; Wu, T.*A Semiconducting Metal-Chalcogenide-Organic Framework with Square-Planar Tetra-coordinated Sulfur. Chem. Commun. 2018,54, 11272-11275.

[8] Zhang, Y. Y.; Wang, X.*; Hu, D. D.; Xue, C. Z.; Wang, W.; Lin, J.; Yang, H. J.;Wu, T.* Monodisperse Ultrasmall Manganese-Doped Multi-metal OxisulfideNanoparticles as Highly Efficient Oxygen Reduction Electrocatalyst. ACS Applied Materials & Interfaces.2018,10, 13413-13424.

[9] Hu, D. D.; Wang, X.; Yang, H. J.; Liu, D. L.; Zhang, Y. Y.; Xue, C. Z.; Wang, W.; Li, D. S.; Wang, Y.; Guo, J.; Wu, T.*Host-Guest Electrocatalyst with Cage-Confined Cu2S Nanoparticles Embeded in Semiconductor Chalcogenide Zeolite for Highly Efficient Oxygen Reduction Reaction. Electrochimica Acta.2018, 282, 877-885.

[10] Xu, X. F.; Hu, D. D.; Xue, C. Z.; Zhang, J. X.; Li, D. S.; Wu, T.*Exploring the Effect of Intercluster Torsion Stress on Mn2+-Related Red Emission from Cluster-based Layered Metal Chalcogenides. J. Mater. Chem. C2018,6, 10480-10485.

[11] Zhang, L.; Xue, C. Z.; Wang, W.; Hu, D. D.; Lv, J.; Wu, T.*A Stable Super-Supertetrahedron with Inifinite Order via Assembly of Supertetrahedral T4 Zinc-Indium Sulfide Clusters. Inorg. Chem. 2018, 57, 10485-10488.

[12] Zhang, J. X.; Wang, W.; Xue, C. Z.; Zhao, M. F.; Hu, D. D.; Lv, J.; Wang, X.; Li, D. S.; Wu, T.* Metal-Chalcogenide Imidazole Frameworks with Hybrid Intercluster Bridging Mode and Unique Interrupted Topological Structure. Inorg. Chem. 2018, 57,9790-9793.

[13] Wang, H. X.; Wang, W.; Hu, D. D.; Luo, M.; Xue, C. Z.; Li, D. S.; Wu, T.*Hybrid Assembly of Different Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn-In-S Open Framework with Large Cavity. Inorg. Chem .201857, 6710-6715.

[14] Lin, J.; Hu, D. D.; Yang, H. J.; Liu, Y.; Xue, C. Z.; Wu, T.* Nonlinear Variation in Composition and Optical Band Gap of Alloyed Cluster-Based Open-Framework Metal Chalcogenide. Inorg. Chem.2018,57, 4248-4251.

[15] Wang, W.; Wang, X.; Hu, D. D.; Yang, H. J.; Xue, C. Z.; Lin, Z. E.; Wu, T.* An Unusual Metal Chalcogenide Zeolitic Framework Built from the Extended Spiro-5 Units with Supertetrahedral Clusters as Node. Inorg. Chem.2018, 57, 921-925.

[16] Lin, J.; Fu, Z. X.; Zhang, J. X.; Zhu, Y. J.; Hu, D. D.; Li, D. S.; Wu, T.* Substituent Modulated Assembly Formation: An Approach to Enhancing the Photostability of Photoelectric Sensitive Chalcogenide-Based Ion-Pair Hybrids. Inorg. Chem.2017, 56, 3119-3122.

[17] Xue, C. Z.; Hu, D. D.; Zhang, Y. Y.; Yang, H. J.*; Wang, X.; Wang, W.; Wu, T.* Two Unique Crystalline Semiconductor Zeolite Analogues Based on Hybrid Indium Selenide Clusters. Inorg. Chem. 2017, 56, 14763-14766.

[18] Yang, H. J.++; Luo, M.++; Chen, X. T.++; Zhao, X.; Lin, J.; Hu, D. D.; Li, D. S.; Bu, X.; Feng, P.*; Wu, T.* Cation-Exchanged Zeolitic Chalcogenide for CO2 Adsorption. Inorg. Chem. 2017, 56, 14999-15005. [++These authors contributed equally to this work.]

[19] Wang, F.++; Lin, J.++; Zhao, T. B.; Hu, D. D.; Wu, T.*; Liu Y.* Intrinsic Vacancy Point Defect Induced Electrochemiluminescence from Coreless Supertetrahedral Chalcogenide Nanocluster. J. Am. Chem. Soc.2016, 138, 7718-7724. [++These authors contributed equally to this work.]

[20] Yang, H. J.; Luo, M.; Luo, L.; Wang, H. X.; Hu, D. D.; Lin, J.; Wang, X.; Wang, Y. L.; Wang, S. A.; Bu, X.*; Feng, P.*; Wu, T.* Highly Selective and Rapid Cesium Uptake of Radionuclide Cesium Based on Robust Zeolitic Chalcogenide via Stepwise Ion-Exchange Strategy. Chem. Mater.2016, 28, 8774-8780.

[21] Yang, H. J.; Wang, L.; Hu, D. D.; Lin, J.; Luo, L.; Wang, H. X.; Wu, T.* A Novel Copper-Rich Open-Framework Chalcogenide Constructed from Octahedral Cu4Se6 and Icosahedral Cu8Se13 Nanocluster. Chem. Comm.2016, 52, 4140-4143. (Inside Cover)

[22] Lin, J.; Hu, D. D.; Zhang, Q.; Li, D. S.; Wu, T.*; Bu, X.; Feng, P.* Improving Photoluminescence Emission Efficiency of Nanocluster Based Materials by In-situ Doping Synthetic Strategy. J. Phys. Chem. C2016, 120, 29390-29396.

[23] Zhang, Q.; Lin, J.; Yang, Y. T.; Qin, Z. Z.; Li, D. S.; Wang, S. A.; Liu, Y. P.; Zou, X. X.; Wu, Y. B.*; Wu, T.* Exploring Mn2+-Location-Dependent Red Emission from (Mn/Zn)-Ga-Sn-S Supertetrahedral Nanocluster with Relatively Precise Dopant Position. J. Mater. Chem. C2016, 4, 10435-10444. (Hot paper, Front Cover)

[24] Lin, J.; Wang, L.; Zhang, Q.; Bu, F.; Wu, T.; Wu, T.*; Bu, X.; Feng, P. Highly Effective Nano-segregation of Dual Dopants in a Micron-Sized Nanocluster-Based Semiconductor Molecular Single Crystal for Targeting White-Light Emission. J. Mater. Chem. C2016, 4, 1645-1650.

[25] Lin, J.++; Dong, Y.-Z.++; Zhang, Q.; Hu, D.-D.; Li, N.; Wang, L.*; Liu, Y.*; Wu, T.* Interrupted Chalcogenide-Based Zeolite-Analog Semiconductor: Atomically Precise Doping for Tunable Electro-/Photo-electrochemical Properties, Angew. Chem. Int. Ed.2015, 54, 5103-5107 (VIP). [++These authors contributed equally to this work.]

[26] Hu, D. D.; Lin, J.; Zhang, Q.; Lu, J. N.; Wang, X. Y.; Wang, Y. W.; Bu, F.; Ding, L. F.; Wang, L.*; Wu, T.* Multi-Step Host-Guest Energy Transfer Between Inorganic Chalcogenide Based Semiconductor Zeolite Material and Organic Dye Molecules. Chem. Mater.2015, 27, 4099-4104.

[27] Hu, D. D.; Wang, L.; Lin, J.; Bu, F.; Wu, T.* Tuning Efficiency of Multi-Step Energy Transfer in Host-Guest Antennae System based on Chalcogenide Semiconductor Zeolite through Acidification and Solvation of Guests. J. Mater. Chem. C2015, 3, 11747-11753.

[28] Lin, J.; Zhang, Q.; Wang, L.; Liu, X.C.; Yan, W.B.; Wu, T.*; Bu, X.*; Feng, P.* Atomically Precise Doping of Mono-manganese Ion into Coreless Supertetrahedral Chalcogenide Nanocluster Inducing Unusual Red Shift in Mn2+ Emission, J. Am. Chem. Soc.2014, 136, 4769-4779.

[29] Wu, T.*; Zhang, Q.; Hou, Y.; Wang, L.; Mao, C.; Zheng, S.; Bu, X.; Feng, P.* Monocopper Doping in Cd-In-S Supertetrahedral Nanocluster via Two-step Strategy and Enhanced Photoelectric Response. J. Am. Chem. Soc.2013, 135, 10250-10253.


第一作者代表性论文:

[1]Wu, T.; Bu, X.; Liao, P.; Wang, L.; Zheng, S.; Ma, R.; Feng, P.* Superbase-Route to Supertetrahedral Chalcogenide Clusters. J. Am. Chem. Soc. 2012, 134, 3619-3622.

[2]Wu, T.; Zuo, F.; Wang, L.; Bu, X.; Zheng, S.; Ma, R.; Feng, P.* A Large Indium Sulfide Supertetrahedral Cluster Built from Integration of ZnS-Like Tetrahedral Shell with NaCl-Like Octahedral Core. J. Am. Chem. Soc.2011, 133, 15886-15889.

[3]Wu, T.; Bu, X.; Zhao, X.; Khazhakyan, R.; Feng, P.* Phase Selection and Site-Selective Distribution by Tin and Sulfur in Supertetrahedral Zinc Gallium Selenides. J. Am. Chem. Soc.2011, 133, 9616-9625.

[4]Wu, T.; Khazhakyan, R.; Wang, L.; Bu, X.; Zheng, S.; Chau, V.; Feng, P.*Three-Dimensional Covalent Co-Assembly between Inorganic Supertetrahedral Clusters and Imidazolates, Angew. Chem. Int. Ed. 2011, 50, 2536-2539.

[5]Wu, T.; Wang, L.; Bu, X.; Chau, V., Feng, P.* Largest Molecular Clusters in Supertetrahedral Tn Series. J. Am. Chem. Soc. 2010, 132, 10823-10831.

[6]Wu, T.; Wang, X. Q.; Bu, X.; Zhao, X.; Wang, L.; Feng, P.* Synthetic Control of Selenide Supertetrahedral Clusters and Three-Dimensional Co-assembly by Charge-Complementary Metal Cations. Angew. Chem. Int. Ed.2009, 48, 7204 -7207.

[7]Wu, T.; Zhang, J.; Zhou, C.; Wang, L.; Bu, X.*; Feng, P.* Zeolite RHO-Type Net with the Lightest Elements.J. Am. Chem. Soc.2009, 131, 6111-6113.

[8]Zhang, J.++; Wu, T.++; Zhou, C.; Chen, S.; Feng, P.*; Bu, X.* Zeolitic Boron Imidazolate Frameworks. Angew. Chem. Int. Ed.2009, 48, 2542-2545. [++ These authors contributed equally to this work.]

(2019-04-15 更新)