Tel: 86-512-65880341 (Lab)

Fax: 86-512-65880305 (O.)

学历及学术经历：1992年18新利体育 化学教育专业本科毕业，1995年18新利体育 有机化学专业毕业，获硕士学位，期间赴南开大学做访问学者1年。1995年留校工作至今，2006年获有机化学博士学位。

主持国家自然科学基金2项，江苏省高校自然18新利备用网站 项目1项，参加2项国家自然科学基金项目和1项省部级项目。在国内外化学核心期刊如Green Chem., Org. Lett., Org. Chem. Front., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等发表论文数十篇，授权发明专利4项。2009年度获江苏省科学技术进步奖二等奖，2010年获得中国石油和化学工业协会科学技术进步奖一等奖。2011年获得江苏政府留学基金资助出国访学。

主要教学成果：

副主编《有机化学实验》（高教出版社），参编《有机化学》（高教出版社）、《有机化学演示实验（音像）》（高教出版社）、《有机化学实验》（南京大学出版社）和《有机硫化学》等教材5部。2000年和2009年两次获得18新利体育 利苏奖教金，2006年获得江苏省高校第三届多媒体课件制作大赛三等奖，2012年获得江苏省优秀毕业设计团队奖，2015年获得江苏省高校微课教学本科组三等奖，2015年获18新利体育 交行教学奖。2005年主持并完成《有机化学（一）》双语课程建设，2007年起主要承担《有机化学》校精品课程建设，2015和2016年分别主持18新利体育 3I工程《有机化学》和《有机化学实验》微课程建设。

研究领域：稀土金属有机化合物的合成、结构及其催化性质，导向有机合成的金属有机化学，不对称合成等。

Representative Publications:

1. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides

L. J. Hu,C. R. Lu,B. Zhao*, Y. M. Yao

Org. Chem. Front., 2018, DOI: 10.1039/C7QO00991G

2. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction

C. Gong, H. Ding, C. R. Lu, B. Zhao*, Y. M. Yao

Dalton Trans., 2017, 46, 6031-6038.

3. Efficient asymmetric hydrophosphonylation of unsaturated amides catalyzed by rare-earth metal amides [(Me₃Si)₂N]₃RE(m-Cl)Li(THF)₃ with phenoxy-functionalized chiral prolinols

Z. H. Fei, C. Zeng, C. R. Lu, B. Zhao*, Y. M. Yao

RSC Adv. 2017, 7, 19306-19311.

4.Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions

B. Zhao,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao

Dalton Trans.2016, 45, 3880-3887.

5. Asymmetric michael addition of malonates to unsaturated ketones catalyzed by rare earth metal complexes bearing phenoxy functionalized chiral diphenylprolinolate ligands

Q. Q. Qian, W. G. Zhu, C. R. Lu, B. Zhao*, Y. M. Yao

Tetrahedron: Asy. 2016, 27, 911-917.

6. Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from CO₂ and 2-aminobenzonitriles

Q. Y. Wang,C. R. Lu,B. Zhao*, Y. M. Yao

Eur. J. Org. Chem., 2016, 2555-2559.

7. Carboxylation of terminal alkynes with CO₂ catalyzed by bis(amidate) rare-earth metal amides

H. Cheng, B. Zhao,* Y. M. Yao, C. R. Lu

Green Chem.,2015, 17, 1675-1682.

8. Highly enantioselective epoxidation of α,β-unsaturated ketones catalyzed by rare-earth amides [(Me₃Si)₂N]₃RE(μ-Cl)Li(THF)₃ with phenoxy-functionalized chiral prolinols

C. Zeng, D. Yuan, B. Zhao,* Y. M. Yao

Org. Lett., 2015, 17, 2242-2245.

9. Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides

H. Cheng, Y. Xiao, C. R. Lu, B. Zhao,* Y. R. Wang, Y. M. Yao

New J. Chem.,2015, 39, 7667-7671.

10. Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide

Y. Cui, W. K. Gu, Y. R. Wang,* B. Zhao,* Y. M. Yao, Q. Shen

Catal. Sci. Technol.,2015, 5, 3302-3312.

11. Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-b-butyrolactone

T. H. Zeng, Q. Q. Qian, B. Zhao,* D. Yuan, Y. M. Yao*, Q. Shen

RSC Adv. 2015, 5, 53161-53171.

12.C-N bond formation reaction catalyzed by Organo-rare-earth metal amides (Invited Review)

Y. Xiao, Q. Y. Wang, B. Zhao*, Y. M. Yao*

Chin. J. Org. Chem. 2015, 35, 1598-1614.

13. Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand

Q. Q. Qian, Y. F. Tan, B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*

Org. Lett., 2014, 16, 4516-4519.

14. Synthesis and characterization of amidate rare-earth metal amides and their catalytic activities towardhydrophosphonylation of aldehydes and unactivated ketones

L. Zhao, H. Ding, B. Zhao,* C. R. Lu, Y. M. Yao

Polyhedron, 2014, 83, 50-59.

15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes with a-carbonyl esters catalyzed by an indium(III)-PyBox complex

B. Zhao, T. P. Loh

Org. Lett.,2013, 15, 2914-2917.

16. Unexpected C−H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene bridged bis(β-diketiminate) ligand

S. Sun, Q. Sun, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*

Organometallics, 2013, 32, 1876-1881.

17. Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides

S. Sun, K. Nie, Y. F. Tan, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*

Dalton Trans., 2013, 42, 2870-2878.

18.Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization of rac-lactide

X. L. Hu, C. R. Lu, B. Wu, H. Ding, B. Zhao*, Y. M. Yao*, Q. Shen

J. Organomet. Chem., 2013, 732, 92-101.

19. Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones

H. Ding, C. R. Lu, X. L. Hu, B. Zhao*, B. Wu, Y. M. Yao*

Synlett, 2013, 24, 1269-1274.

20. Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex

B. Zhao, X. L. Hu, C. R. Lu

J. Appl. Polym. Sci., 2011, 120, 2693.

21. One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation

C. R. Lu, B. Zhao*, Y. P. Jiang, H. Ding, S. Yang

Syn. Commun.,2011, 41, 1257.

22.Ring-opening polymerization of trimethylenecarbonate and its copolymerization with e-caprolactone by lanthanide (II) aryloxide complexes

B. Zhao, C. R. Lu, Q. Shen

J. Appl. Polym. Sci., 2007, 106, 1383.

23. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ₂-p-(Me₃SiN)₂C₆H₄}YbCl(THF)₂]₂ and [{μ₂-p-(Me₃SiN)₂C₆H₄}Nd(μ₂-Cl)(THF)]₄•2PhMe

B. Zhao, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu

Organometallics,2006, 25, 1824.

24. Polymerization of N-phenyl maleimide by lanthanide complexes

B. Zhao, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng

J.Polym. Sci. Polym. Chem.,2005, 43, 3966.